As a result of the significant disruption that is being caused by the COVID-19 pandemic we are very aware that many researchers will has difficulty in meeting the timelines associated with our peer review process during normal times.  Please do let us know if you need additional time. Our systems will continue to remind you of the original timelines but we intend to be highly flexible at this time.

A b s t r a c t

In the present paper, a simple and sensitive method for simultaneous preconcentration and determination of lead and copper by flame atomic absorption spectrometry was developed. This method was based on solid phase extraction of lead and copper with 1-nitroso-2-naphthol-3,6-disulfonic acid chelate on naphthalene column. After preconcentration stage, the column was eluted by 5 mL of 1.2 mol L-1 nitric acid solution and metal ions directly determined by flame atomic absorption spectrometry. The effect of different variables such as pH, sample volume, amount of chelate, flow rate and eluent solution on the recovery of the analyte was investigated. The detection limits were 0.7 and 0.5 μg L-1 for lead and copper, respectively. The relative standard deviations of the determinations for analyte ions were below 4 %. This procedure was applied to the determination of lead and copper in water samples. The results demonstrated that the procedure can be applied for analysis of waters with satisfactory accuracy.

Authors

H. ZAVVAR MOUSAVI and H. SHIRKHANLOO

ACKNOWLEDGEMENT

The financial support of this work by Semnan University Research Council is greatly acknowledged.

Download Paper

Contact us

Journal Publisher: AMEC Publisher as a privet international publisher from Iran. Publisher Link click here.

Madadkaran Alley,Farjam St., Shahnazari Ave, Mirdamad, 

Tehran, Iran     P: 1545653718