Investigation of Adsorption of Cobalt-phthalocyanine from Aqueous Waste Stream Using UVM-7/Ag
Volume1,Issue01,Pages29-38,Ar-AMC-34 *** Filed: Environmental Analysis
Abstract
The effect adsorption of cobalt-phthalocyanine-3,4’,4”,4”’- tetrasulfonicacid tetrasodium salt [Co(tsPc)-4•4Na＋] onto UVM-7/Ag mesoporous material was investigated. In addition, X-ray diffraction (XRD), scanning electron microscopy (SEM), and nitrogen adsorptiondesorption measurement were used to examine the morphology and the microstructure of the obtained composite. Various parameters including solution adsorbent dosage, contact time, initial dye concentration and temperature were systematically studied. Equilibrium data fitted well the Langmuir models; moreover, the fitness suggests that the adsorption be monolayer and physical in nature. Kinetic studies showed that the adsorption process could be better described by the Lagergren pseudosecond- order models. Thermodynamic constant values (ΔG < 0, ΔH< 0 and ΔS< 0) demonstrated that the adsorption reactions of Co(tspc)-4 onto UVM-7/Ag were feasible, spontaneous, and exothermic under the examined conditions.
References
M. Mirzaeian, A.M. Rashidi, M. Zare, R. Ghabezi, R. Lotfi, Mercaptan removal from natural gas using carbon nanotube supported cobalt phthalocyanine nanocatalyst, J. Natur. Gas Sci. Eng., 18 (2014) 439-445.
M. Chanda, A. Grinshpun, K. O’driscoll, G. Rempel, Polymer-supported metal complexes as catalysts for the oxidation of thiosalts by molecular oxygen: V. The polythiosemicarbazide-Cu (II) complex, J. Mol. Catal., 26 (1984) 267-76.
N. Reid , R. Barat, Impact of Fluorinated Cobalt(II) Phthalocyanine Catalysts on Aerobic Thiol Oxidation Kinetics, Chem. Eng. Commun., 203 (2016) 714-723.
V. Iliev, Catalytic oxidation of mercaptans by charcoal-supported sterically hindered cobalt (II)-phthalocyanines,
J. mol.catal., 85 (1993) L269-L273.
D. Klyamer, A. Sukhikh, S. Gromilov , P. Krasnov , T. Basova , Fluorinated metal phthalocyanines: interplay between fluorination degree, films orientation, and ammonia sensing properties, Sensors, 18 (2018) 1-13.
A.B. Sorokin, Phthalocyanine metal complexes in catalysis, Chem. Rev., 113 (2013) 8152-8191.
B. Basu, S. Satapathy, A. Bhatnagar, Merox and related metal phthalocyanine catalyzed oxidation processes, Catal. Rev. Sci. Eng., 35 (1993) 571-609.
Z. Tang, W. Wu, K. Wang, Review: oxygen reduction reaction catalyzed by noble metal clusters, Catalysts, 8 (2018) 1-18.
Y. Cheng, J. Veder, L. Thomsen, S. Zhao, M. Saunders,
R. Demichelis, C. Liu, R. De Marco, S. P. Jiang, Electrochemically substituted metal phthalocyanines, e-MPc (M = Co, Ni), as highly active and selective catalysts for CO2 reduction, J. Mater. Chem. A, 6 (2018) 1370-1375.
A. Leitão, A. Rodrigues, Studies on the Merox process: Kinetics of n-butyl mercaptan oxidation, Chem. Eng. Sci., 44 (1989) 1245-1253.
T. Wallace, A. Schriesheim, H. Hurwitz, M. Glaser, Base-Catalyzed Oxidation of Mercaptans in Presence of Inorganic Transition Metal Complexes, Ind. Eng. Chem. Process Des. Dev., 3 (1964) 237-241.
M. Anbia, K. Mohammadi, An effective method for removal of dichromate ion and furfural from aqueous solutions using a nanoporous adsorbent, Asian J. Chem., 21(2009) 3347-3356.
M. Anbia, M.K. Rofouei, S.W. Husain, Mesoporous lanthanum tungstate as a novel sorbent for removal of heavy metal ions from aqueous media. Asian J. Chem., 19 (2007) 3862-3873.
D. Zhao, G. Sheng, J. Hu, C. Chen, X. Wang, The adsorption of Pb (II) on Mg 2 Al layered double hydroxide, Chem. Eng. J., 171(2011) 167-74.
M.T. Yagub, T.K. Sen, S. Afroze, H.M. Ang, Dye and its removal from aqueous solution by adsorption: a review, Adv. Coll. Int. Sci., 209 (2014)172-184.
A. Srivastav, V.C. Srivastava, Adsorptive desulfurization by activated alumina, J. Hazard. Mater., 170 (2009) 1133-1140.
Y. Önal, Kinetics of adsorption of dyes from aqueous solution using activated carbon prepared from waste apricot, J. Hazard. Mater., 137 (2006) 1719-1728.
M. Anbia, S.A. Hariri, Removal of methylene blue from aqueous solution using nanoporous SBA-3, Desalination, 261(2010) 61-66.
A. Sari, D. Mendil, M. Tuzen, M. Soylak, Biosorption of palladium (II) from aqueous solution by moss (Racomitrium lanuginosum) biomass: equilibrium, kinetic and thermodynamic studies. J. Hazard. Mater., 162 (2009) 874-879.
K. Foo, B. Hameed, Insights into the modeling of adsorption isotherm systems, Chem. Eng. J., 156 (2010) 2-10.
V. M. Abbasov, H. C. Ibrahimov, Adsorptive Desulfurization of the Gasoline Obtained from Low-Pressure Hydro cracking of the Vacuum Residue Using a Nickel/Bentonite Catalyst, Energy Fuels, 31 (2017) 5840–5843.
Y. Yongxing, J. Li, L. Guangqian, L. Zhang, Novel method to synthesize Ni2P/SBA-15 adsorbents for the adsorptive desulfurization of model diesel fuel, J. Alloys Compd., 745 (2018) 467-476.
C. Almeida, N. Debacher, A. Downs, L. Cottet, C. Mello, Removal of methylene blue from colored effluents by adsorption on montmorillonite clay, J. coll. Int. Sci., 332 (2009) 46-53.
N.R. Shinde, A.V. Bankar, A.R. Kumar, S.S. Zinjarde, Removal of Ni (II) ions from aqueous solutions by biosorption onto two strains of Yarrowia lipolytica, J. Environ. Manage., 102 (2012) 115-124.
A. Bera, T. Kumar, K. Ojha, A. Mandal, Adsorption of surfactants on sand surface in enhanced oil recovery: isotherms, kinetics and thermodynamic studies, Appl. Surf. Sci., 284 (2013) 87-99.
[ R. Labied, O. Benturki, A. E.Hamitouche, Adsorption of hexavalent chromium by activated carbon obtained from a waste lignocellulosic material: Kinetic, equilibrium, and thermodynamic study, Adsorp. Sci. Technol., 36 (2018) 1066–1099.
A. Dada, A. Olalekan, A. Olatunya, O. Dada, Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk, J. Appl. Chem., 3 (2012) 38-45.
A. Rong, L. Meng, P. Liping, Y. Dongsheng, J. Wang , Y. Zhou, Kinetics Study of Gas Pollutant Adsorption and Thermal Desorption on Silica Gel, Appl. Sci., 7, 609 (2017) 1-11.
M. Anbia, A.H. Davijani, Synthesis of L-Cysteine grafted nanoporous carbon (CMK-3) and its use as a new cadmium sorbent, Chem. Eng. J., 223(2013) 899-907.
M. Gouamid, M. Ouahrani, M. Bensaci, Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using date palm leaves, Energy Procedia, 36(2013) 898-907.
JOURNAL PUBLISHING AGREEMENT
PLEASE PROVIDE US THE FOLLOWING INFORMATION,
Article entitled:
Corresponding author:
To be published in the journal:
Your Status
I am the sole author of the manuscript
- I am an Iranian government employee.
- I am a European government employee
- I am a Asian government
- None of the above
I am one author signing on behalf of all co-authors of the manuscript
- I am an Iranian government employee.
- I am a European government employee
- I am a Asian government
- None of the above
Please tick the above blanks (as appropriate), review the Journal Publishing Agreement, and then sign and date the document in black ink.
Published Journal Article: the author may share a link to the formal publication through the relevant DOI. Additionally theses and dissertations which contain embedded Published Journal Articles as part of the formal submission may be hosted publicly by the awarding institution with a link to the formal publication through the relevant DOI. Any other sharing of Published Journal Articles is by agreement with the publisher only.
Signed: ______________________________________ Name printed: ___________________________________________
Title and Company (if employer representative): _______________________Date: __________________________________
