Separation of aniline from water and wastewater samples based on activated carbon nanoparticles and dispersive solid phase extraction procedure

Volume 3, Issue 04, Pages 72-84, Dec 2020 *** Field: Environmental Analytical Chemistry

  • Saeed Fakhraie, (*Corresponding Author) Chemistry Department, Yasouj University, P.O. Box 74831-75918, Yasouj, Iran.
  • Morteza Mehdipour Rabouri Occupational Health Engineering Department, , Kerman University of Medical Sciences, Kerman, Iran
  • Ahmad Salarifar Environmental Engineering, Faculty of Natural Resources, Islamic Azad University, Bandar Abbas Branch, Iran
DOI: https://doi.org/10.24200/amecj.v3.i04.126
Keywords: Aniline, Activated carbon nanoparticles, Ionic liquid, Dispersive solid phase extraction procedure, gas chromatography–mass spectrometry

Abstract

The water, wastewater and air are the main sources of aniline in environment. Aniline has a toxic effect in the human body and environment and so, must be determined by novel techniques. In this study, the activated carbon with microwave heating methods (MHM-ACNPs) were used for extraction aniline from waters by dispersive ionic liquid solid phase extraction procedure (D-IL-SPE) and compared to the activated carbon (AC). For this purpose, the mixture of acetone, ionic liquid and 30 mg of MHM-ACNPs/AC added to 100 mL of water samples at pH=8. After sonication for 10 min, the benzene ring in aniline as electron acceptor was chemically adsorbed on carboxylic groups of MHM-ACNPs as electron donors (MHM-ACNPs-COO─……C6H5-NH2) and then, the adsorbent was collected by IL phase in bottom of conical centrifuging tube. Finally, the aniline was released from MHM-ACNPs in remained solution by changing pH and the concentration of aniline determined by GC-FID.

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Published
2020-12-29
How to Cite
Fakhraie, S., Mehdipour Rabouri, M., & Salarifar, A. (2020). Separation of aniline from water and wastewater samples based on activated carbon nanoparticles and dispersive solid phase extraction procedure. Analytical Methods in Environmental Chemistry Journal, 3(04), 72-84. https://doi.org/10.24200/amecj.v3.i04.126
Issue
Vol 3 No 04 (2020): Issue No. four
Section
Original Article

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